Cyclobutyl chloride
- CasNo:1120-57-6
Product Description
China cas 1120-57-6 manufacturer wholesale Cyclobutyl chloride at affordable price
- Molecular Formula: C4H7 Cl
- Molecular Weight: 90.5526
- Appearance/Colour: clear colorless liquid
- Vapor Pressure: 85.6mmHg at 25°C
- Melting Point: 155-156 °C
- Refractive Index: n20/D 1.436(lit.)
- Boiling Point: 83 ºC
- Flash Point: -9 ºC
- PSA： 0.00000
- Density: 0.991
- LogP: 1.77770
Cyclobutyl chloride(Cas 1120-57-6) Usage
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Synthesis Reference(s) |
Synthetic Communications, 20, p. 1011, 1990 DOI: 10.1080/00397919008052804 |
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General Description |
Cyclobutyl chloride is formed by rearrangements concerted with fragmentation of cyclopropylmethoxychlorocarbene and cyclobutoxychlorocarbene. The thermal decomposition of cyclobutyl chloride was investigated over the temperature range of 892-1150K using very low-pressure pyrolysis technique. |
InChI:InChI=1/C4H7Cl/c5-4-2-1-3-4/h4H,1-3H2
1120-57-6 Relevant articles
Fragmentation of cyclobutoxychlorocarbene: The cyclopropylcarbinyl/cyclobutyl cations revisited
Moss, Robert A.,Zheng, Fengmei,Johnson, Lauren A.,Sauers, Ronald R.
, p. 400 - 406 (2001)
Fragmentations of cyclobutoxychlorocarbe...
Rearrangement, nucleophilic substitution, and halogen switch reactions of alkyl halides over NaY zeolite: Formation of the bicyclobutonium cation inside the zeolite cavity
Franco, Marcelo,Rosenbach Jr., Nilton,Ferreira, Glaucio B.,Guerra, Antonio C. O.,Kover, W. Bruce,Turci, Cassia C.,Mota, Claudio J. A.
, p. 1592 - 1600 (2008)
Rearrangement and nucleophilic substitut...
ELECTROPHILIC ADDITION TO BICYCLOBUTANE>
Abramova, N. M.,Zotova, S. V.,Nesmeyanova, O. A.
, p. 961 - 964 (1982)
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Rearrangements concerted with fragmentation of cyclopropylmethoxychlorocarbene and cyclobutoxychlorocarbene in hydrocarbon solvents and Ar matrices
Moss, Robert A.,Sauers, Ronald R.,Zheng, Fengmei,Fu, Xiaolin,Bally, Thomas,Maltsev, Alexander
, p. 8466 - 8476 (2004)
Fragmentations of cyclopropylmethoxychlo...
Free radical chain reactions of chlorine with cyclobutane in the solid state: Evidence for radical migration via H atom transfer
Sedlacek, Arthur J.,Wight, Charles A.
, p. 2847 - 2848 (1988)
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Walling,Fredricks
, p. 3326,3331 (1962)
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Olah,Lin
, p. 6468 (1968)
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Fragmentation of alkoxychlorocarbenes in the gas phase
Blake, Michael E,Jones Jr., Maitland,Zheng, Fengmei,Moss, Robert A
, p. 3069 - 3071 (2007/10/03)
In contrast to photolysis or thermal dec...
1120-57-6 Process route
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122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine
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-
927-73-1
3-butenyl chloride
-
-
1120-57-6
chlorocyclobutane
-
-
5911-08-0
chloro(cyclopropyl)methane
| Conditions | Yield |
|---|---|
|
In
acetonitrile;
at 25 ℃;
|
15 % Chromat.
7 % Chromat. 78 % Chromat. |
|
With
tetrabutylammonium tetrafluoroborate;
In
acetonitrile;
at 25 ℃;
|
64 % Chromat.
27 % Chromat. 9 % Chromat. |
|
With
tetrabutylammonium tetrafluoroborate;
In
acetonitrile;
at 25 ℃;
|
64 % Chromat.
9 % Chromat. 27 % Chromat. |
-
-
75637-38-6
cyclopropylcarbinol hypochlorite
-
-
927-73-1
3-butenyl chloride
-
-
1120-57-6
chlorocyclobutane
-
-
5911-08-0
chloro(cyclopropyl)methane
| Conditions | Yield |
|---|---|
|
With
triphenyl phosphite;
In
dichloromethane;
at -78 ℃;
|
8.5 % Chromat.
1.5 % Chromat. 90 % Chromat. |
1120-57-6 Upstream products
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287-23-0
cyclobutane
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127-08-2
potassium acetate
-
64-19-7
acetic acid
-
5911-08-0
chloro(cyclopropyl)methane
1120-57-6 Downstream products
-
5911-08-0
chloro(cyclopropyl)methane
-
1506-77-0
1,1‐dichlorocyclobutane
-
31038-07-0
1-Bromo-1-chlorocyclobutane
-
13372-19-5
cis-1,3-Dichlorcyclobutan