3-Benzyloxy-1,2-propanediol
- CasNo:4799-67-1
Product Description
Factory Sells Best Quality 3-Benzyloxy-1,2-propanediol 4799-67-1 with GMP standards
- Molecular Formula: C10H14O3
- Molecular Weight: 182.219
- Vapor Pressure: 1.17E-05mmHg at 25°C
- Melting Point: 62.7-63.4 °C
- Refractive Index: n20/D 1.533
- Boiling Point: 355.1 °C at 760 mmHg
- PKA: 13.65±0.20(Predicted)
- Flash Point: 168.6 °C
- PSA： 49.69000
- Density: 1.16 g/cm3
- LogP: 0.55640
3-Benzyloxy-1,2-propanediol(Cas 4799-67-1) Usage
|
General Description |
(±)-3-Benzyloxy-1,2-propanediol undergoes enantioseparation by ligand exchange micellar electrokinetic chromatography using borate anion as a central ion. |
InChI:InChI=1/C10H14O3/c11-6-10(12)8-13-7-9-4-2-1-3-5-9/h1-5,10-12H,6-8H2
4799-67-1 Relevant articles
Dendritic Oligoglycerol Regioisomer Mixtures and Their Utility for Membrane Protein Research
Urner, Leonhard H.,Goltsche, Katharina,Selent, Marleen,Liko, Idlir,Schweder, Marc-Philip,Robinson, Carol V.,Pagel, Kevin,Haag, Rainer
, p. 2537 - 2542 (2020/12/30)
Dendrons are an important class of macro...
Synthesis and catalytic evaluation of acidic carbons in the etherification of glycerol obtained from biodiesel production
Chiosso, María E.,Casella, Mónica L.,Merlo, Andrea B.
, p. 107 - 114 (2020/10/29)
In this paper, the catalytic behaviour o...
Selective monochlorination of unsymmetrical vicinal diols with chlorinated iminium chlorides
Li, Chengyang,Li, Xiaotong,Wang, Yu,Wu, Xiaoyu,Xie, Xiaomin,Yang, Liqun,Zhang, Zhaoguo
supporting information, (2020/03/23)
Chlorinated iminium chlorides have been ...
POLY(PHOSPHOESTERS) FOR DELIVERY OF NUCLEIC ACIDS
-
, (2020/09/15)
Disclosed are polymers comprising the mo...
4799-67-1 Process route
-
-
2930-05-4
Benzyloxymethyl-oxiran
-
-
13071-59-5,17325-85-8,56552-80-8,4799-67-1
3-benzyloxypropan-1,2-diol
| Conditions | Yield |
|---|---|
|
With
sulfuric acid;
In
water;
at 20 ℃;
for 5h;
|
96%
|
|
With
perchloric acid; water;
at 80 ℃;
|
90%
|
|
With
perchloric acid;
In
water;
at 80 ℃;
|
90%
|
|
With
perchloric acid;
In
diethyl ether;
at 20 ℃;
|
77%
|
|
With
water; iodine;
In
acetonitrile;
for 3h;
Heating;
|
63%
|
|
With
potassium hydroxide;
In
dimethyl sulfoxide;
at 100 ℃;
|
46%
|
|
sulfuric acid;
In
water; acetone;
for 3h;
Yield given;
Heating;
|
|
|
With
base or acid;
|
|
|
With
perchloric acid;
In
water;
at 80 ℃;
for 12h;
|
|
|
With
perchloric acid;
In
water; benzene;
|
264 g (90%)
|
|
With
sulfuric acid;
at 20 ℃;
for 5h;
|
|
|
Multi-step reaction
with
2
steps
1: lithium tert-butoxide; copper(l) iodide / tetrahydrofuran / 20 h / 60 °C / Schlenk technique; Inert atmosphere
2: sodium hydroxide; dihydrogen peroxide / tetrahydrofuran / 10 h / 0 - 20 °C / Schlenk technique; Inert atmosphere
With
copper(l) iodide; dihydrogen peroxide; sodium hydroxide; lithium tert-butoxide;
In
tetrahydrofuran;
|
|
|
With
water;
at 25 ℃;
pH=7.2;
enantioselective reaction;
Microbiological reaction;
Enzymatic reaction;
|
-
-
100-39-0
benzyl bromide
-
-
100-79-8,36543-79-0
(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol
-
-
13071-59-5,17325-85-8,56552-80-8,4799-67-1
3-benzyloxypropan-1,2-diol
| Conditions | Yield |
|---|---|
|
(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol;
With
sodium hydride;
In
tetrahydrofuran; N,N-dimethyl-formamide; mineral oil;
at 0 ℃;
benzyl bromide;
In
tetrahydrofuran; N,N-dimethyl-formamide; mineral oil;
at 0 - 20 ℃;
for 3h;
With
acetic acid;
In
water;
at 20 ℃;
for 24h;
|
97%
|
|
(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol;
With
sodium hydride;
In
N,N-dimethyl-formamide;
at 0 ℃;
for 0.166667h;
benzyl bromide;
In
N,N-dimethyl-formamide;
for 5h;
|
77%
|
|
(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol;
With
sodium hydride;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 0.5h;
Inert atmosphere;
Schlenk technique;
benzyl bromide;
In
tetrahydrofuran;
Inert atmosphere;
Schlenk technique;
|
60%
|
4799-67-1 Upstream products
-
556-52-5
oxiranyl-methanol
-
100-51-6
benzyl alcohol
-
15028-56-5
4-(benzyloxymethyl)-2,2-dimethyl-1,3-dioxolane
-
100-44-7
benzyl chloride
4799-67-1 Downstream products
-
103397-09-7
1-O-benzyl-2,3-di-O-dodecanoyl-rac-glycerol
-
60276-38-2
1-[(2,3-dibromopropoxy)methyl]benzene
-
60656-87-3
benzyloxyacetoaldehyde
-
209802-30-2
(+/-)-1-benzyloxy-2,3-bis-methanesulfonyloxy-propane