What is the PIPERITONE?

PIPERITONE is clear, light yellowish to yellow liquid, while it's Molecular Formula is C 10 H 16 O. clear, light yellowish to yellow liquid Piperitone is a monoterpene compound that has a fresh minty camphor-like odour, and naturally occurs in extracts of commercial oil of peppermint. Piperitone is also used as a starting material in the synthesis of Thymol (T413000), a phenolic compound that is used for its antibacterial properties.

What is the CAS number for PIPERITONE?

The CAS number of PIPERITONE is 89-81-6.

What is PIPERITONE (89-81-6) used for?

PIPERITONE is a p-menthane monoterpenoid with a fresh minty camphor-like odor, naturally occurring in extracts of commercial oil of peppermint. It is a primary reference substance with assigned absolute purity, and its exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG, PIPERITONE is a cyclohex-2-en-1-one substituted by a methyl group at position 3 and an isopropyl group at position 6.InChI:InChI=1/C10H16O/c1-7(2)9-5-4-8(3)6-10(9)11/h6-7,9H,4-5H2,1-3H3

What is the PIPERITONE?

PIPERITONE is clear, light yellowish to yellow liquid, while it's Molecular Formula is C 10 H 16 O. clear, light yellowish to yellow liquid Piperitone is a monoterpene compound that has a fresh minty camphor-like odour, and naturally occurs in extracts of commercial oil of peppermint. Piperitone is also used as a starting material in the synthesis of Thymol (T413000), a phenolic compound that is used for its antibacterial properties.

What is the CAS number for PIPERITONE?

The CAS number of PIPERITONE is 89-81-6.

What is PIPERITONE (89-81-6) used for?

PIPERITONE is a p-menthane monoterpenoid with a fresh minty camphor-like odor, naturally occurring in extracts of commercial oil of peppermint. It is a primary reference substance with assigned absolute purity, and its exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG, PIPERITONE is a cyclohex-2-en-1-one substituted by a methyl group at position 3 and an isopropyl group at position 6.InChI:InChI=1/C10H16O/c1-7(2)9-5-4-8(3)6-10(9)11/h6-7,9H,4-5H2,1-3H3

PIPERITONE

CasNo:89-81-6

Product Description

Reputable supplier selling PIPERITONE 89-81-6 with stock

Molecular Formula:C₁₀H₁₆O
Molecular Weight:152.236
Appearance/Colour:clear, light yellowish to yellow liquid
Vapor Pressure:0.0572mmHg at 25°C
Melting Point:-29ºC
Refractive Index:-60 ° (C=4, benzene)
Boiling Point:233ºC
Flash Point:90.9 ºC
PSA：17.07000
Density:0,93g/cm³
LogP:2.56780

PIPERITONE(Cas 89-81-6) Usage

Definition	ChEBI: A p-menthane monoterpenoid that is cyclohex-2-en-1-one substituted by a methyl group at position 3 and an isopropyl group at position 6.
General Description	This substance is a primary reference substance with assigned absolute purity (considering chromatographic purity, water, residual solvents, inorganic impurities). The exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG

InChI:InChI=1/C10H16O/c1-7(2)9-5-4-8(3)6-10(9)11/h6-7,9H,4-5H2,1-3H3

89-81-6 Relevant articles

Synthesis of Cyclic Enones by Allyl-Palladium-Catalyzed α,β-Dehydrogenation

Huang, David,Zhao, Yizhou,Newhouse, Timothy R.

supporting information, p. 684 - 687 (2018/02/09)

The use of allyl-palladium catalysis for...

Allyl-Palladium-Catalyzed Ketone Dehydrogenation Enables Telescoping with Enone α,β-Vicinal Difunctionalization

Chen, Yifeng,Huang, David,Zhao, Yizhou,Newhouse, Timothy R.

supporting information, p. 8258 - 8262 (2017/06/30)

The telescoping of allyl-palladium catal...

Hydrolytic enantioselective protonation of cyclic dienyl esters and a β-diketone with chiral phase-transfer catalysts

Yamamoto, Eiji,Gokuden, Daichi,Nagai, Ayano,Kamachi, Takashi,Yoshizawa, Kazunari,Hamasaki, Akiyuki,Ishida, Tamao,Tokunaga, Makoto

supporting information, p. 6178 - 6181 (2013/02/25)

Hydrolytic enantioselective protonation ...

3-Alkyl-p-menthan-3-ol derivatives: synthesis and evaluation of their physiological cooling activity

Fuganti, Claudio,Joulain, Daniel,Maggioni, Francesco,Malpezzi, Luciana,Serra, Stefano,Vecchione, Andrea

body text, p. 2425 - 2437 (2009/04/06)

Different 3-alkyl-p-methan-3-ol derivati...

89-81-6 Process route

: 1068-55-9
isopropylmagnesium chloride

: 6-chloro-3-methylcyclohex-2-en-1-one

: 89-81-6,6091-52-7
piperitone

Conditions

Conditions	Yield
isopropylmagnesium chloride; With zinc dibromide; In diethyl ether; at 0 ℃; for 0.5h; 6-chloro-3-methylcyclohex-2-en-1-one; With copper acetylacetonate; In diethyl ether; at 25 ℃; for 14h;	45%

: 491-09-8
3-terpinolenone

: 89-81-6,6091-52-7
piperitone

: 89-82-7,90449-51-7
pulegone

: 17627-49-5,7786-64-3
cis-5-methyl-2-(1-methylethyl)cyclohexanone

: 17627-49-5,7786-64-3
trans-5-methyl-2-(1-methylethyl)cyclohexanone

Conditions

Conditions	Yield
With cyclohexyl(triphenyl)phosphonium bromide; hydrogen; di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium; (S)-2,2'-bis-1,1'-binaphthyl; In tetrahydrofuran; at 50 ℃; for 18h; under 22502.3 Torr;
With N-benzyl-N,N,N-triethylammonium chloride; hydrogen; di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium; (S)-2,2'-bis-1,1'-binaphthyl; In tetrahydrofuran; at 50 ℃; for 18h; under 22502.3 Torr;
With cyclohexyl(triphenyl)phosphonium bromide; hydrogen; di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium; (S)-2,2'-bis-1,1'-binaphthyl; In acetone; at 50 ℃; for 18h; under 22502.3 Torr;
With cyclohexyl(triphenyl)phosphonium bromide; hydrogen; rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate; (S)-2,2'-bis-1,1'-binaphthyl; In tetrahydrofuran; at 50 ℃; for 18h; under 22502.3 Torr;
With cyclohexyl(triphenyl)phosphonium bromide; hydrogen; di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium; 2,2'-bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1-binaphthyl; In tetrahydrofuran; at 50 ℃; for 18h; under 22502.3 Torr;
With cyclohexyl(triphenyl)phosphonium bromide; hydrogen; ((5,6),(5'6')-bis(methylenedioxy)biphenyl-2,2'-diyl)bis(di3,5-di-tert-butyl-4-methjxyphenylphosphine); C₄F₇O₂^(1-)*C₁₆H₂₄Rh⁽¹⁺⁾; In tetrahydrofuran; at 50 ℃; for 18h; under 22502.3 Torr;